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61.
A Tale of Copper Coordination Frameworks: Controlled Single‐Crystal‐to‐Single‐Crystal Transformations and Their Catalytic CH Bond Activation Properties 下载免费PDF全文
Yifa Chen Prof. Xiao Feng Prof. Xianqiang Huang Zhengguo Lin Xiaokun Pei Siqing Li Jikun Li Shan Wang Rui Li Prof. Bo Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(40):13894-13899
Metal–organic frameworks (MOFs), as a class of microporous materials with well‐defined channels and rich functionalities, hold great promise for various applications. Yet the formation and crystallization processes of various MOFs with distinct topology, connectivity, and properties remain largely unclear, and the control of such processes is rather challenging. Starting from a 0D Cu coordination polyhedron, MOP‐1, we successfully unfolded it to give a new 1D‐MOF by a single‐crystal‐to‐single‐crystal (SCSC) transformation process at room temperature as confirmed by SXRD. We also monitored the continuous transformation states by FTIR and PXRD. Cu MOFs with 2D and 3D networks were also obtained from this 1D‐MOF by SCSC transformations. Furthermore, Cu MOFs with 0D, 1D, and 3D networks, MOP‐1, 1D‐MOF, and HKUST‐1, show unique performances in the kinetics of the C?H bond catalytic oxidation reaction. 相似文献
62.
Mesoporous Carbon Nanofibers Embedded with MoS2 Nanocrystals for Extraordinary Li‐Ion Storage 下载免费PDF全文
Dr. Shan Hu Prof. Wen Chen Dr. Evan Uchaker Prof. Jing Zhou Prof. Guozhong Cao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(50):18248-18257
MoS2 nanocrystals embedded in mesoporous carbon nanofibers are synthesized through an electrospinning process followed by calcination. The resultant nanofibers are 100–150 nm in diameter and constructed from MoS2 nanocrystals with a lateral diameter of around 7 nm with specific surface areas of 135.9 m2 g?1. The MoS2@C nanofibers are treated at 450 °C in H2 and comparison samples annealed at 800 °C in N2. The heat treatments are designed to achieve good crystallinity and desired mesoporous microstructure, resulting in enhanced electrochemical performance. The small amount of oxygen in the nanofibers annealed in H2 contributes to obtaining a lower internal resistance, and thus, improving the conductivity. The results show that the nanofibers obtained at 450 °C in H2 deliver an extraordinary capacity of 1022 mA h g?1 and improved cyclic stability, with only 2.3 % capacity loss after 165 cycles at a current density of 100 mA g?1, as well as an outstanding rate capability. The greatly improved kinetics and cycling stability of the mesoporous MoS2@C nanofibers can be attributed to the crosslinked conductive carbon nanofibers, the large specific surface area, the good crystallinity of MoS2, and the robust mesoporous microstructure. The resulting nanofiber electrodes, with short mass‐ and charge‐transport pathways, improved electrical conductivity, and large contact area exposed to electrolyte, permitting fast diffusional flux of Li ions, explains the improved kinetics of the interfacial charge‐transfer reaction and the diffusivity of the MoS2@C mesoporous nanofibers. It is believed that the integration of MoS2 nanocrystals and mesoporous carbon nanofibers may have a synergistic effect, giving a promising anode, and widening the applicability range into high performance and mass production in the Li‐ion battery market. 相似文献
63.
通过缓慢滴加焦磷酸钾的硝酸溶液到钼酸铵溶液中制得了大颗粒磷钼酸铵(AMP)。研究了AMP的成核速率(G)与晶体生长速率。与晶体生长速率相比成核速率的反应级数更高。最初,大颗粒磷钼酸铵的结晶过程处于相变反应控制的动力学区域,此时溶液的过饱和生成速率比过饱和消除速率高。晶体线生长速率与溶液的过饱和度先增加后降低。在滴加中期,过饱和消除速率增长到与其生成速率相当。在滴加后期,晶体成核速率快速增高,而晶体的线生长速率下降。晶体的成核速率成为过饱和消除的唯一控制步骤。因此,AMP成核大部分是在首先接触到滴加液的局部溶液中完成的。 相似文献
64.
A palladium-catalyzed ortho-selective C–H bond chlorination reaction for the preparation of 2-chloro aromatic ketones was described. Both electron-withdrawing and electron-donating groups on the aromatic rings are well tolerated under the optimized conditions. The 2-chloro aromatic ketones obtained by our method could be applied to synthesize the derivatives of 1H-indazole or benzo[d]isoxazole. 相似文献
65.
通过丙烯酰胺(AM),丙烯酸(AA),烯丙醇聚氧乙烯醚(APEG)和N,N-二烯丙基苄胺(NANB)制备共聚物P(AM/AA/APEG/NANB)。确定了最佳反应条件:m(AM)∶m(AA)=6.5∶3,APEG为5 wt%,NANB加量0.2 wt%,pH为7,反应温度40℃,引发剂0.4 wt%。通过IR和1H NMR确定了聚合物的分子结构,并对其进行性能测试。结果表明:2000 mg·L-1的AM/AA/APEG/NANB溶液具有较好的流变性能(120℃,粘度保留率:38.56%;1000 s-1,粘度保留率:17.93%)和抗盐性能(20 000 mg·L-1Na Cl,2000 mg·L-1Mg Cl2或Ca Cl2,粘度保留率分别为22.14%、18.34%和15.33%),且提高采收率可达16.12%。 相似文献
66.
An Antibacterial Nonenzymatic Glucose Sensor Composed of Carbon Nanotubes Decorated with Silver Nanoparticles 下载免费PDF全文
Yingzhu Liu Shan Liu Rongsheng Chen Weiting Zhan Hongwei Ni Feng Liang 《Electroanalysis》2015,27(5):1138-1143
A glucose sensor composed of silver nanoparticles decorated carbon nanotubes (Ag‐NPs/CNTs) prepared by ion implantation is described. Ag‐NPs with size of 2–4 nm are uniformly distributed in the CNTs after ion implantation. This process provides a strong combination between Ag‐NPs and CNTs and can effectively prevent the Ag‐NPs from aggregation. A linear range of 125 µM to 10 mM towards glucose determination was obtained. The Ag‐NPs/CNTs electrode shows minimal interferences from co‐existence species such as uric acid and ascorbic acid and an antibacterial rate of 94 % towards E. coli. 相似文献
67.
Multifunctional Nano‐Bioprobes Based on Rattle‐Structured Upconverting Luminescent Nanoparticles 下载免费PDF全文
Dr. Shan Lu Dr. Datao Tu Ping Hu Jin Xu Renfu Li Dr. Meng Wang Dr. Zhuo Chen Prof. Mingdong Huang Prof. Dr. Xueyuan Chen 《Angewandte Chemie (International ed. in English)》2015,54(27):7915-7919
Lanthanide‐doped upconversion nanoparticles (UCNPs) have shown great promise in versatile bioapplications. For the first time, organosilica‐shelled β‐NaLuF4:Gd/Yb/Er nanoprobes with a rattle structure have been designed for dual‐modal imaging and photodynamic therapy (PDT). Benefiting from the unique rattle structure and aromatic framework, these nanoprobes are endowed with a high loading capacity and the disaggregation effect of photosensitizers. After loading of β‐carboxyphthalocyanine zinc or rose Bengal into the nanoprobes, we achieved higher energy transfer efficiency from UCNPs to photosensitizers as compared to those with conventional core–shell structure or with pure‐silica shell, which facilitates a large production of singlet oxygen and thus an enhanced PDT efficacy. We demonstrated the use of these nanoprobes in proof‐of‐concept X‐ray computed tomography (CT) and UC imaging, thus revealing the great potential of this multifunctional material as an excellent nanoplatform for cancer theranostics. 相似文献
68.
69.
XianaiaoLiu HuizhouLiu JianminXing YuepingGuan ZhiyaMa GuobinShan chengliYang 《中国颗粒学报》2003,1(2):76-79
Superparamagnetic poly(styrene-divinylbenzene-glycidyl methacrylate) (Pst-DVB-GMA) microparticles were prepared via a modified suspension polymerization process. A magnetic fluid was first prepared by a chemical co-precipitation method. Then magnetic microparticles were produced by mixing the monomers and the magnetic fluid with water in the presence of a stabilizer poly(vinyl pyrrolidone) (PVP) to form a suspension, and finally benzoyl peroxide was added to initiate the co-polymerization. The morphology and magnetic properties of the microparticles were examined by TEM and VSM. The spherically shaped microparticles, with a size range of 4 to 7 pm, showed distinct superparamagnetic characteristics. XRD was used to investigate the structure of the magnetite particles dispersed in the polymer matrix. The microparticles with epoxy groups on their surface can be applied directly to the seoaration of biomolecules. 相似文献
70.
Periodic Solutions of Delay Differential Equations with a Small Parameter: Existence,Stability and Asymptotic Expansion 总被引:1,自引:0,他引:1
Chunhua?Ou Jianhong?WuEmail author 《Journal of Dynamics and Differential Equations》2004,16(3):605-628
We consider a scalar delay differential equation with a small parameter, and employ Walthers method to obtain a result on the existence and stability of a slowly oscillatory periodic solution that represents a refinement of the estimate for the Lipschitz constant of a returning map. We also develop a matching method and obtain asymptotic expansions of the slowly oscillatory periodic solution and its minimal period.Dedicated to Professor Shui-Nee Chow on the occasion of his 60th birthdayAMS subject classifications: 34K15; 34K20; 34C25. 相似文献